Paper I — Q5
(a) Assume that the Earth's atmosphere is pure nitrogen in thermodynamic equilibrium at a temperature of 300 K. Calculate the…
Assume that the Earth's atmosphere is pure nitrogen in thermodynamic equilibrium at a temperature of 300 K. Calculate the height above sea level at which the density of the atmosphere is one-half its sea level value. (Molecular weight of N₂ is 28 gm/mole) 10 marks
A body of constant heat capacity Cₚ and a temperature Tᵢ is put into contact with a reservoir at temperature Tƒ. Equilibrium between the body and the reservoir is established at constant pressure. Determine the total entropy change and prove that it is positive for either sign of [(Tƒ — Tᵢ)/Tƒ]. Consider |Tƒ — Tᵢ|/Tƒ < 1. 10 marks
Consider two point particles of charge q each, separated by a distance d, and travelling at non-relativistic velocity v⃗. If the line joining the two charges is perpendicular to v⃗, then write an expression for the magnetic force between the two particles, and illustrate the direction of the force on each particle. 10 marks
A cell of internal resistance 1 ohm, 1·5 volt e.m.f. and another cell of internal resistance 2 ohm, 2 volt e.m.f. are connected in parallel across the ends of an external resistance of 5 ohm. Find the current in each branch of the circuit. 10 marks
Consider the R-L-C circuit shown here. Calculate the Q-factor of the circuit. Does the circuit have a resonant frequency? Justify your answer : 10 marks
हिंदी में प्रश्न पढ़ें
मान लीजिए कि पृथ्वी का वायुमंडल 300 K के तापमान पर ऊष्मागतिक साम्य में शुद्ध नाइट्रोजन है। समुद्र-तल से ऊँचाई की गणना कीजिए जिस पर वायुमंडल का घनत्व उसके समुद्र-तल मान का आधा है। (N₂ का आण्विक भार 28 gm/mole है) (10 अंक)
नियत ऊष्मा धारिता Cₚ और तापमान Tᵢ का एक पिंड तापमान Tƒ पर एक भंडार (जलाशय) के संपर्क में आता है। अचल दाब पर पिंड और भंडार के बीच साम्यावस्था स्थापित होती है। कुल एन्ट्रॉपी परिवर्तन का निर्धारण कीजिए और सत्यापित कीजिए कि यह [(Tƒ — Tᵢ)/Tƒ] के किसी भी चिह्न के लिए धनात्मक है। मान लीजिए कि |Tƒ — Tᵢ|/Tƒ < 1 है। (10 अंक)
विचारिए कि दो बिंदु कण जिनमें प्रत्येक का आवेश q है, d दूरी से पृथक्कृत और अनापेक्षिकीय वेग v⃗ से गति कर रहे हैं। यदि दोनों आवेशों को मिलाने वाली रेखा v⃗ के लम्बवत् है, तो दोनों कणों के बीच चुंबकीय बल के लिए व्यंजक लिखिए और प्रत्येक कण पर बल की दिशा का वर्णन कीजिए। (10 अंक)
1·5 वोल्ट विद्युत वाहक बल तथा 1 ओम आंतरिक प्रतिरोध का एक सेल और 2 वोल्ट विद्युत वाहक बल तथा 2 ओम आंतरिक प्रतिरोध का दूसरा सेल 5 ओम के बाह्य प्रतिरोध के सिरों पर समांतर क्रम में जुड़े हुए हैं। परिपथ की प्रत्येक शाखा में धारा का मान ज्ञात कीजिए। (10 अंक)
चित्र में दिखाए गए R-L-C परिपथ पर विचार कीजिए। परिपथ के Q-गुणक की गणना कीजिए। क्या परिपथ में अनुनादी आवृत्ति होती है? उत्तर का औचित्य दीजिए : (10 अंक)
The figure this question refers to, in words
The question paper is a scan and the diagram did not survive as text. This is the figure as read from the original page — every component, value and label — so the question can be worked from the text below.
(e) A circuit diagram showing a DC voltage source labeled '4 V' connected in series with a switch labeled 'K'. The switch connects to a parallel circuit configuration. One branch of the parallel section contains an inductor labeled '1 mH' in series with a resistor labeled '4 Ohm'. The other branch contains a capacitor labeled '2 mF'. The bottom of the parallel branches connects back to the negative terminal of the voltage source.
Model answer
Drafted with AI by UPSC Answer Check against this question's marking rubric, to the expected length. UPSC does not publish answers for Mains — this is one way to score well, not an official key. How we build rubrics and answers.
(a) To calculate the height at which the atmospheric density is half its sea-level value, we assume an isothermal atmosphere in thermodynamic equilibrium. The density ρ at height h is given by the barometric formula: ρ = ρ₀ exp(-Mgh/RT) where M is the molar mass, g is gravitational acceleration, R is the gas constant, and T is the temperature. We are given T = 300 K, M = 28 g/mol = 0.028 kg/mol, and g = 9.8 m/s². Setting ρ = ρ₀ / 2: 1/2 = exp(-Mgh/RT) Taking the natural logarithm of both sides: ln(2) = Mgh/RT implies h = RT/Mg ln(2) Substituting the values: h = (8.314 × 300)/(0.028 × 9.8) × 0.693 h = 2494.2/0.2744 × 0.693 ≈ 9089.6 × 0.693 ≈ 6300 m The height is approximately 6.30 km. This result is physically consistent with the scale height of the atmosphere.
(b) The total entropy change is the sum of the entropy change of the body and the reservoir. For the body at constant pressure, the change is: Δ S_body = Cₚ ln((T_f)/(Tᵢ)) The reservoir at constant temperature T_f gives up heat Q = Cₚ(T_f - Tᵢ), so its entropy change is: Δ Sᵣₑₛ = -Q/(T_f) = -(Cₚ(T_f - Tᵢ))/(T_f) The total entropy change is: Δ Sₜₒₜₐₗ = Cₚ ln((T_f)/(Tᵢ)) - (Cₚ(T_f - Tᵢ))/(T_f) Let x = (T_f - Tᵢ)/(T_f). Then (T_f)/(Tᵢ) = 1/(1-x). The expression becomes: (Δ Sₜₒₜₐₗ)/(Cₚ) = ln(1/(1-x)) - x = -ln(1-x) - x Using the Taylor expansion -ln(1-x) = x + (x²)/2 + (x³)/3 + …, we get: (Δ Sₜₒₜₐₗ)/(Cₚ) = (x²)/2 + (x³)/3 + … For small |x| the leading term x²/2 is positive. More generally, let f(x) = −ln(1−x) − x for x below 1. Then f(0) = 0 and f′(x) = x/(1−x), which is negative for x below 0 and positive for x above 0, so f has its minimum 0 at x = 0. Hence ΔS_total is positive for either sign of (T_f − Tᵢ)/T_f, and zero only when T_f = Tᵢ, as the second law requires.
(c) Consider two point charges q moving with velocity v⃗. The magnetic field produced by one charge at the location of the other, separated by distance d, is given by the Biot-Savart law for a moving charge: B⃗ = (μ₀)/(4π) (q (v⃗ × r̂))/(d²) The magnetic force on the second charge is F⃗ = q v⃗ × B⃗. Since the line joining the charges is perpendicular to v⃗, the magnitude of the force is: F = q v B = q v ( (μ₀)/(4π) qv/(d²) ) = (μ₀)/(4π) (q² v²)/(d²) The direction of the force is determined by the cross product. For two charges moving in the same direction, the magnetic force is attractive, acting toward each other. This is analogous to the attraction between parallel currents. The electric repulsion q²/(4πε₀d²) is larger by c²/v², so the net force is still repulsive: F_mag/F_el = v²/c².
(d) Let I₁ be the current from the 1.5 V cell, I₂ from the 2 V cell, and I₃ through the 5 Ω resistor. Applying Kirchhoff's Current Law (KCL) at the node: I₁ + I₂ = I₃ Applying Kirchhoff's Voltage Law (KVL) to the first loop (1.5 V cell and 5 Ω resistor): 1.5 = I₁(1) + I₃(5) Applying KVL to the second loop (2 V cell and 5 Ω resistor): 2 = I₂(2) + I₃(5) Substituting I₃ = I₁ + I₂:
- 1.5 = I₁ + 5(I₁ + I₂) = 6I₁ + 5I₂
- 2 = 2I₂ + 5(I₁ + I₂) = 5I₁ + 7I₂ Solving this system: From (1), I₁ = (1.5 - 5I₂)/6. Substituting into (2): 2 = 5((1.5 - 5I₂)/6) + 7I₂ implies 12 = 7.5 - 25I₂ + 42I₂ implies 17I₂ = 4.5 I₂ = 4.5/17 ≈ 0.265 A I₁ = (1.5 - 5(0.265))/6 = 0.175/6 ≈ 0.029 A I₃ = 0.029 + 0.265 = 0.294 A
(e) With the switch K, the 4 V source charges the circuit, and when K is opened the inductor (with its 4 Ω resistance) and the capacitor form a closed series R-L-C loop. Equivalently, for sinusoidal excitation the R-L branch is in parallel with C. The resonant frequency ω₀ is determined by the condition where the imaginary part of the admittance is zero. The undamped natural frequency is ω₀ = 1/(√LC); for this configuration the actual resonance condition is ω_r² = 1/(LC) − R²/L². Given L = 1 mH = 10⁻³ H and C = 2 mF = 2 × 10⁻³ F: ω₀ = 1/(√(10⁻³ × 2 × 10⁻³)) = 1/(√(2 × 10⁻⁶)) = 1000/(√2) ≈ 707 rad/s The Q-factor for a parallel RLC circuit (where R is in series with L) is given by Q = (ω₀ L)/R. Q = (707 × 10⁻³)/4 = 0.707/4 ≈ 0.18 Equivalently, Q = (1/R)√(L/C) = (1/4)√(0.5) ≈ 0.177. The circuit does not have a resonant frequency. For the R-L-C loop, critical damping needs R = 2√(L/C) = 1.41 Ω, and here R = 4 Ω is larger, so the loop is overdamped (Q below 1/2): the capacitor discharges without oscillation. For sinusoidal drive, R² = 16 Ω² exceeds L/C = 0.5 Ω², so 1/(LC) − R²/L² is negative and the susceptance never vanishes.
How this answer will be evaluated
What earns full marks: Rigorous derivation, correct units, clear diagrams, and physical interpretation for all parts.
Evaluation rubric
Each sub-part is marked on its own, against the marks and word limit printed on the paper.
- (a) Height where atmospheric density is half the sea-level value. 10 marks
calculate— given → formula → substitution → result with units → interpretation
Must cover
- State barometric formula or derive from hydrostatic equilibrium
- Substitute T=300K, M=28g/mol, g=9.8m/s²
- Solve for h using ln(2) or log(2)
- Final answer in km with units
Loses marks
- Using wrong molecular weight (e.g. 14g/mol)
- Forgetting to convert grams to kg in M
Earns more
- Explicitly state assumption of isothermal atmosphere
- Show dimensional check of the exponent
Extra mark
- Mention scale height H = kT/mg
- (b) Total entropy change and proof of positivity for both signs. 10 marks
derive— given → assumptions → stepwise derivation → result → check
Must cover
- Calculate ΔS_body = Cp ln(Tf/Ti)
- Calculate ΔS_res = -Cp(Tf-Ti)/Tf
- Sum to get ΔS_total expression
- Prove ΔS_total > 0 using Taylor expansion or inequality
Loses marks
- Sign error in reservoir entropy change
- Failing to prove positivity for both signs
Earns more
- Explicitly handle case Ti > Tf and Ti < Tf
- Use the condition |Tf-Ti|/Tf < 1 in the proof
Extra mark
- Relate result to the Second Law of Thermodynamics
- (c) Expression for magnetic force and direction on each particle. 10 marks
explain— definition/context → points in order → small example → short close
Must cover
- Use Biot-Savart law or magnetic field of moving charge
- Apply Lorentz force F = qv × B
- Derive F ∝ v²/d (or similar) with correct vector direction
- Illustrate direction (attractive/repulsive) with a diagram
Loses marks
- Wrong direction of force (e.g. repulsive instead of attractive)
- Missing the v² dependence
Earns more
- Explicitly state the perpendicular geometry condition
- Mention non-relativistic approximation
Extra mark
- Compare magnitude with electrostatic force
- (d) Current in each branch of the parallel circuit. 10 marks
calculate— given → formula → substitution → result with units → interpretation
Must cover
- Apply Kirchhoff's Current Law (KCL) at the node
- Apply Kirchhoff's Voltage Law (KVL) for each loop
- Solve the system of linear equations for I1, I2, I3
- State currents with direction and units (A)
Loses marks
- Sign error in KVL equations
- Ignoring internal resistances
Earns more
- Draw the circuit diagram with labelled currents
- Check power balance (P_in = P_out)
Extra mark
- Calculate terminal voltage across the 5Ω resistor
- (e) Q-factor and justification for resonant frequency existence. 10 marks
calculate— given → formula → substitution → result with units → interpretation
Must cover
- Identify the L-R branch and C forming a loop (series RLC on opening K, R-L parallel C for a.c.)
- Calculate Q = (1/R)√(L/C) ≈ 0.18
- Calculate resonant frequency ω0 = 1/sqrt(LC)
- Justify no resonance: R = 4 Ω exceeds 2√(L/C) = 1.41 Ω (overdamped), or ω² = 1/LC − R²/L² negative
Loses marks
- Using Q = R√(C/L) (ideal parallel RLC) for this circuit
- Failing to justify the resonant frequency claim
Earns more
- Show the formula for Q in parallel RLC
- Calculate numerical value of ω0 in rad/s
Extra mark
- Mention bandwidth Δω = ω0/Q
What "Calculate" is asking you to do
Apply the standard formula or schedule to data the question has already supplied — a table of readings, cost records, a balance sheet — and produce the number. The method is rarely in doubt; the marks sit in the named intermediate quantities, each of which has to appear as a labelled line.
Structure that answers it
Data as given → formula or standard treatment, named → substitution → each intermediate, labelled → result with units
Where marks are lost
Omitting an intermediate the marking scheme pays for separately, or rounding at an intermediate line so the final figure drifts. In commerce and accountancy, any figure in a statement that no numbered working note supports is treated as unearned.
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