Physics

UPSC Physics 2022

All 16 questions from the 2022 Civil Services Mains Physics paper across 2 papers — 800 marks in total. Each question comes with a detailed evaluation rubric, directive word analysis, and model answer points.

16Questions
800Total marks
2Papers
2022Exam year

Paper I

8 questions · 400 marks
Q1
50M Compulsory solve Classical mechanics and special relativity

An electron is moving under the influence of a point nucleus of atomic number Z. Show that the orbit of the electron is an ellipse. 10 marks Show that the mean kinetic and potential energies of non-dissipative simple harmonic vibrating systems are equal. 10 marks An observer on a railway platform observed that as a train passed through the station at 108 km/hr, the frequency of the whistle appeared to drop by 350 Hz. Find the frequency of the whistle. (Velocity of sound in air = 380 m s⁻¹) 10 marks Show that for very small velocity, the equation for kinetic energy, K = Δmc² becomes K = ½m₀v², where notations have their usual meanings. 10 marks A phase retardation plate of quartz has thickness 0·1436 mm. For what wavelength in the visible region will it act as quarter-wave plate? Given that μ₀ = 1·5443 and μᴇ = 1·5533. 10 marks

Answer approach & key points

This question demands solving five distinct 10-mark problems covering classical mechanics and special relativity. The answer should present each solution as a self-contained unit with clear problem identification, step-by-step working, and final boxed answers. Begin with the orbital mechanics problem (Kepler's first law derivation), followed by the SHM energy theorem, then the Doppler effect calculation, the relativistic kinetic energy approximation, and finally the quarter-wave plate wavelength determination. Conclude with a brief synthesis noting the unifying theme of oscillatory and wave phenomena across the problems.

  • For the electron orbit: Apply Newton's second law with Coulomb force, use polar coordinates, and derive the orbit equation r(θ) = l/(1+εcosθ) showing ε<1 for bound states
  • For SHM energies: Derive ⟨T⟩ and ⟨V⟩ over one complete period using x = Asin(ωt+φ), showing both equal ¼kA² or ¼mω²A²
  • For Doppler effect: Identify this as a moving source problem (observer stationary), apply f' = f[v/(v±vs)] with proper sign convention for approaching/receding train
  • For relativistic KE: Expand γ = (1-v²/c²)^(-½) using binomial theorem, keeping terms up to v²/c² to recover classical result
  • For quarter-wave plate: Use condition (μe-μo)t = λ/4, solve for λ = 4(μe-μo)t, and verify result falls in visible range (400-700 nm)
Q2
50M calculate Rotating frames, collision dynamics and optics

Consider two frames of reference S and S' having a common origin O. The frame S' is rotating with respect to the fixed frame S with a uniform ω⃗ = 3aₓ rad s⁻¹. A projectile of unit mass at position vector r⃗ = 7aₓ + 4aᵧ m is moving with v⃗ = 14aᵧ m s⁻¹. Calculate in the rotating frame S' the following forces on the projectile: (i) Euler's force (ii) Coriolis force (iii) Centrifugal force 15 marks A particle P of mass m₁ collides with another particle Q of mass m₂ at rest. The particles P and Q travel at angles θ and φ, respectively, with respect to the initial direction of P. Derive the expression for the maximum value of θ. 15 marks Obtain the system matrix for a thick lens and derive the thin lens formula. 20 marks

Answer approach & key points

Begin with a brief statement of the rotating frame transformation equations and collision kinematics principles. Allocate approximately 30% time to Part 1 (rotating frame forces with explicit vector calculations), 30% to Part 2 (collision geometry derivation with momentum conservation), and 40% to Part 3 (thick lens matrix method leading to thin lens limit). Present derivations step-by-step with clear identification of final expressions, and conclude with a verification check for the thin lens limit.

  • Part 1: Correct identification that Euler's force is zero for uniform ω, and calculation of Coriolis force (-2mω⃗×v⃗') and centrifugal force (-mω⃗×(ω⃗×r⃗)) with proper vector cross products
  • Part 1: Explicit computation showing v⃗' = v⃗ - ω⃗×r⃗ = 14aᵧ - 12aᵧ = 2aᵧ m/s, yielding Coriolis force = -12a_z N and centrifugal force = 84a_x + 48a_y N
  • Part 2: Application of momentum conservation in x and y directions and kinetic energy conservation (elastic collision) to establish tanθ = sin(2φ)/(m₁/m₂ + cos(2φ))
  • Part 2: Derivation of maximum θ condition leading to sinθ_max = m₂/m₁ when m₁ > m₂, with physical constraint that scattering is impossible if m₁ < m₂
  • Part 3: Construction of system matrix M = R₂T(d)R₁ for thick lens with two refractions and translation, using refraction matrix R = [[1, 0], [(n₁-n₂)/n₂R, n₁/n₂]] and translation matrix T = [[1, d/n], [0, 1]]
  • Part 3: Reduction to thin lens formula 1/f = (n-1)(1/R₁ - 1/R₂) by taking d→0 limit and identifying focal length from matrix element C = -1/f
Q3
50M derive Moment of inertia tensor, Newton's rings, He-Ne laser

(a) A homogeneous right triangular pyramid with the base side $a$ and height $\dfrac{3a}{2}$ is shown below. Obtain the moment of inertia tensor of the pyramid : 20 marks (b) Newton's rings are observed between a spherical surface of radius of curvature 100 cm and a plane glass plate. The diameters of 4th and 15th bright rings are 0·314 cm and 0·574 cm, respectively. Calculate the diameters of 24th and 36th bright rings and also the wavelength of light used. 15 marks (c) In He-Ne laser, what is the function of He gas? Explain the answer with the help of energy level diagram for He-Ne laser. 15 marks

Answer approach & key points

Derive requires systematic mathematical derivation with logical progression. Allocate approximately 40% time to part (a) for the moment of inertia tensor derivation using appropriate coordinate system and integration; 30% to part (b) for Newton's rings calculation with proper formula application and error propagation; 30% to part (c) for explaining He-Ne laser mechanism with energy level diagram. Structure: begin with coordinate setup for (a), proceed through integration, then solve (b) step-by-step showing diameter calculations, conclude with laser physics explanation and diagram.

  • Part (a): Set up coordinate system with origin at apex or centroid, establish limits for triangular pyramid geometry, compute I_xx, I_yy, I_zz and off-diagonal elements using volume integral ∫ρ(r)(r²δ_ij - x_i x_j)dV
  • Part (a): Apply parallel axis theorem if needed and present final 3×3 symmetric inertia tensor matrix with elements in terms of M and a
  • Part (b): Use modified Newton's rings formula for bright rings D_n² = 4(n-½)λR, set up simultaneous equations using n=4 and n=15 data to find λ and verify consistency
  • Part (b): Calculate D_24 and D_36 using derived λ, showing propagation of significant figures and physical reasonableness check (D_n ∝ √n)
  • Part (c): Explain He as buffer gas providing efficient excitation transfer via resonant collision to Ne 2s and 3s levels, preventing depopulation of lower levels
  • Part (c): Draw accurate energy level diagram showing He 2³S, 2¹S metastable states, collisional transfer to Ne 3s₂, 2s₂ upper laser levels, and transitions for 632.8 nm (3s₂→2p₄) and 1.15 μm, 3.39 μm lines with radiative decay to 1s ground state
Q4
50M derive Fluid dynamics, Fraunhofer diffraction, Special relativity

(a) Consider the diagram below with a water flow rate Q. Derive the expression for Q in terms of the difference in the manometer heights h and the cross-section areas A₁ and A₂ : 15 marks (b) Discuss the phenomenon of Fraunhofer diffraction at a single slit and show that the intensities of successive maxima are nearly in the ratio 1 : 4/9π² : 4/25π² : 4/49π² 20 marks (c) Two spaceships approach each other, both moving with same speed as measured by a stationary observer on the Earth. Their relative speed is 0·7c. Determine the velocity of each spaceship as measured by the stationary observer on the Earth. 15 marks

Answer approach & key points

Begin with a concise introduction linking the three phenomena—fluid dynamics, wave optics, and relativistic kinematics—as exemplars of classical and modern physics. Allocate approximately 30% of effort to part (a) deriving the Venturi flow rate, 40% to part (b) discussing Fraunhofer diffraction with intensity derivation, and 30% to part (c) solving the relativistic velocity transformation. For (b), note that 'discuss' requires qualitative explanation before the mathematical proof, while (c) demands explicit calculation with proper velocity addition formula.

  • Part (a): Apply Bernoulli's equation and continuity equation between the two cross-sections, incorporate the manometer height difference h = (p₁-p₂)/ρg, and derive Q = A₁A₂√(2gh/(A₁²-A₂²))
  • Part (b): Explain Fraunhofer diffraction conditions (plane wave, distant screen/lens), derive intensity distribution I(θ) = I₀(sinβ/β)² where β = (πa sinθ)/λ, locate secondary maxima by tanβ = β approximation, and prove the intensity ratio 1 : 4/9π² : 4/25π² : 4/49π²
  • Part (c): Apply Einstein velocity addition formula u' = (u-v)/(1-uv/c²), set up equations with v = ±V (Earth frame), relative speed 0.7c, and solve quadratic to obtain V ≈ 0.41c for each spaceship
  • Explicit statement of assumptions: incompressible, steady, irrotational flow for (a); far-field approximation, monochromatic source for (b); inertial frames, isotropic c for (c)
  • Dimensional verification of final expressions and physical reasonableness checks (e.g., Q→0 as h→0; intensity maxima decrease; V < c always)
Q5
50M Compulsory calculate Thermodynamics, electromagnetism and circuit analysis

(a) Assume that the Earth's atmosphere is pure nitrogen in thermodynamic equilibrium at a temperature of 300 K. Calculate the height above sea level at which the density of the atmosphere is one-half its sea level value. (Molecular weight of N₂ is 28 gm/mole) (10 marks) (b) A body of constant heat capacity Cₚ and a temperature Tᵢ is put into contact with a reservoir at temperature Tƒ. Equilibrium between the body and the reservoir is established at constant pressure. Determine the total entropy change and prove that it is positive for either sign of [(Tƒ — Tᵢ)/Tƒ]. Consider |Tƒ — Tᵢ|/Tƒ < 1. (10 marks) (c) Consider two point particles of charge q each, separated by a distance d, and travelling at non-relativistic velocity v⃗. If the line joining the two charges is perpendicular to v⃗, then write an expression for the magnetic force between the two particles, and illustrate the direction of the force on each particle. (10 marks) (d) A cell of internal resistance 1 ohm, 1·5 volt e.m.f. and another cell of internal resistance 2 ohm, 2 volt e.m.f. are connected in parallel across the ends of an external resistance of 5 ohm. Find the current in each branch of the circuit. (10 marks) (e) Consider the R-L-C circuit shown here. Calculate the Q-factor of the circuit. Does the circuit have a resonant frequency? Justify your answer : (10 marks)

Answer approach & key points

This is a multi-part calculation-based question requiring precise derivations and numerical solutions. Allocate approximately 20% time to each sub-part (a)-(e), with slightly more attention to (b) for its entropy proof and (e) for the missing diagram interpretation. Begin each part with the relevant fundamental equation, show complete derivation steps, substitute values with units, and conclude with physical interpretation of results.

  • (a) Apply barometric formula/ Boltzmann distribution: ρ(h) = ρ₀exp(-mgh/kBT) or n(h) = n₀exp(-Mgh/RT); solve for h when ρ/ρ₀ = 1/2 using m = 28×10⁻³/NA kg
  • (b) Calculate entropy change of body: ΔS_body = Cₚln(Tf/Ti); entropy change of reservoir: ΔS_res = -Cp(Tf-Ti)/Tf; total ΔS = Cₚ[ln(Tf/Ti) - (Tf-Ti)/Tf]; expand ln(1+x) for |Tf-Ti|/Tf < 1 to prove positivity
  • (c) Use Biot-Savart law for moving charge: B = (μ₀/4π)qv×r̂/r²; magnetic force F = qv×B; derive F = (μ₀q²v²)/(4πd²) with direction along line joining charges (attractive for parallel currents)
  • (d) Apply Kirchhoff's laws: set up junction equation I = I₁ + I₂ and loop equations; solve simultaneous equations for I₁, I₂ and I through 5Ω resistor
  • (e) Calculate Q-factor = (1/R)√(L/C) or ω₀L/R; identify whether series or parallel RLC configuration; discuss resonant frequency ω₀ = 1/√(LC) existence based on circuit topology
Q6
50M derive Maxwell equations, thermodynamics and heat capacities

(a) Write down Maxwell's equations in a non-conducting medium with constant permeability and susceptibility (ρ = j = 0). Show that E⃗ and B⃗ each satisfies the wave equation, and find an expression for the wave velocity. Write down the plane wave solutions for E⃗ and B⃗, and show how E⃗ and B⃗ are related. (15 marks) (b) (i) One mole of gas obeys van der Waals equation of state. If its molar internal energy is given by u = cT – a/V (in which V is the molar volume, a is one of the constants in the equation of state and c is a constant), calculate the molar heat capacities Cv and Cp. (10 marks) (ii) A compressor designed to compress air is used instead to compress helium. It is found that the compressor overheats. Explain this effect, assuming that the compression is approximately adiabatic and the starting pressure is same for both the gases. [γHe = 5/3, γAir = 7/5] (10 marks) (c) A gas of interacting atoms has an equation of state and heat capacity at constant volume given by the expressions $$p(T, V) = aT^{1/2} + bT^3 + cV^{-2}$$ $$C_v(T, V) = dT^{1/2} + eT^2V + fT^{1/2}$$ where $a$ through $f$ are constants which are independent of $T$ and $V$. Find the differential of the internal energy $dU(T, V)$ in terms of $dT$ and $dV$. (15 marks)

Answer approach & key points

Derive the required expressions systematically across all four sub-parts, allocating approximately 30% time to part (a) for Maxwell's equations and wave derivations, 20% each to (b)(i) and (b)(ii) for thermodynamic derivations and physical explanations, and 30% to part (c) for the internal energy differential. Begin with stating fundamental equations, proceed through rigorous mathematical steps, and conclude with physical interpretations of results.

  • Part (a): Write all four Maxwell's equations in source-free non-conducting medium; derive wave equations for E⃗ and B⃗ using vector identities; obtain wave velocity c = 1/√(με); write plane wave solutions E⃗ = E⃗₀exp[i(k⃗·r⃗ - ωt)] and B⃗ = B⃗₀exp[i(k⃗·r⃗ - ωt)]; show E⃗ and B⃗ are mutually perpendicular and perpendicular to propagation direction with |E|/|B| = c
  • Part (b)(i): Apply first law and definition Cv = (∂u/∂T)v to get Cv = c; use thermodynamic identity Cp - Cv = T(∂p/∂T)v(∂v/∂T)p with van der Waals equation to derive Cp = c + R/(1 - 2a(v-b)²/RTv³) or appropriate approximation
  • Part (b)(ii): Explain that for adiabatic compression T₂/T₁ = (P₂/P₁)^(γ-1)/γ; since γ_He = 5/3 > γ_Air = 7/5, helium has higher temperature rise for same pressure ratio; compressor designed for air overheats with helium due to greater heating
  • Part (c): Apply fundamental relation dU = Cv dT + [T(∂p/∂T)v - p]dV; compute (∂p/∂T)v = a/(2T^(1/2)) + 3bT²; substitute to get dU = (d+eT²V+f)T^(1/2)dT + [(a/(2T^(1/2)) + 3bT²)T - aT^(1/2) - bT³ - cV^(-2)]dV and simplify
Q7
50M solve Electromagnetic induction, thermodynamics, boundary conditions

(a) A metal guitar string with a length of 70 cm vibrates at its fundamental frequency of 246.94 Hz in a uniform magnetic field of 10 T oriented perpendicular to the plane of vibration of the string. Assume a sinusoidal form for the amplitude of the vibrational mode, and a maximum displacement of 3 mm at the centre of the string. What is the maximum e.m.f. generated across the length of the guitar string, and at what point in time in the string's motion does that occur? What would be the e.m.f. if the same guitar string vibrates at its second harmonic frequency? Briefly explain. (20 marks) (b) A thermally insulated cylinder, closed at both ends, is fitted with a frictionless heat-conducting piston which divides the cylinder in two parts. Initially, the piston is clamped in the centre, with one litre of air at 200 K and 2 atm pressure on one side and one litre of air at 300 K and 1 atm pressure on the other side. The piston is released and the system reaches equilibrium in pressure and temperature, with the piston at a new position. Compute the final pressure and temperature. (15 marks) (c) A current sheet having $\vec{K} = 9.0 a_y$ A m⁻¹ is located at z = 0. The interface is between the region 1, z < 0, $\mu_{r_1} = 4$, and region 2, z > 0, $\mu_{r_2} = 3$. Given that $\vec{H}_2 = 14.5 a_x + 8.0 a_z$ A m⁻¹. Find $\vec{H}_1$ and $\vec{B}_1$. (15 marks)

Answer approach & key points

Solve this multi-part numerical problem by allocating approximately 40% of effort to part (a) given its 20 marks, and 30% each to parts (b) and (c). Begin with clear identification of governing equations for each sub-part, proceed through systematic derivation with proper unit handling, and conclude with boxed final answers and brief physical explanations. For (a), explicitly state when maximum emf occurs; for (b), apply energy conservation and ideal gas law; for (c), use magnetic boundary conditions with proper vector notation.

  • Part (a): Apply motional emf formula ε = Blv using instantaneous velocity of vibrating string element; recognize velocity is maximum at equilibrium position (y=0) giving maximum emf; calculate second harmonic emf noting frequency doubles but amplitude typically reduces
  • Part (a): Correctly integrate over string length with sinusoidal amplitude profile y(x,t) = y_max sin(πx/L)cos(ωt), finding v_max = ωy_max at antinode; emf_max = Bωy_maxL/π for fundamental
  • Part (b): Apply first law of thermodynamics for isolated system (ΔU=0); use n₁CvΔT₁ + n₂CvΔT₂ = 0 for temperature equilibrium; apply ideal gas law with total volume constraint for final pressure
  • Part (b): Recognize piston is heat-conducting so final temperatures equalize, and frictionless mechanical equilibrium gives equal final pressures; solve simultaneous equations for p_f and T_f
  • Part (c): Apply magnetic boundary conditions: normal B continuous (B₁z = B₂z), tangential H discontinuous by surface current (aₙ × (H₂ - H₁) = K); correctly handle vector cross product with K = 9.0 a_y
  • Part (c): Calculate H₁x and H₁z components separately using μ₁H₁ = μ₂H₂ for normal component and H₂x - H₁x = K for tangential; then find B₁ = μ₀μ_r₁H₁
Q8
50M solve Electromagnetic waves, negative temperature, Laplace equation

(a) In a partially conducting medium, $\varepsilon_r = 18.5$, $\mu_r = 800$ and $\sigma = 1$ S m⁻¹. Find α, β, η and the velocity u, for a frequency of 10⁹ Hz. Determine $\vec{H}(z, t)$. Given, $\vec{E}(z, t) = 50 e^{-\alpha z} \cos(\omega t - \beta a_z) a_y$ V m⁻¹. (20 marks) (b) What do you understand by negative temperature? Write and explain various restrictions on a system for the concept of negative temperature to be meaningful. (15 marks) (c) Starting from the Laplace's equation in a cylindrical polar coordinate system and using the method of separation of variables, obtain the differential equations for the solutions of r, φ and z components of the potential. (15 marks)

Answer approach & key points

Begin with a brief introduction acknowledging the three distinct domains: electromagnetic wave propagation in lossy media, statistical mechanics of negative temperature, and electrostatic boundary value problems. Allocate approximately 40% of effort to part (a) given its 20 marks and computational demands; 30% each to parts (b) and (c). For (a), systematically calculate loss tangent, then α, β, η, and u before deriving H(z,t). For (b), define negative temperature and enumerate the three key restrictions (finite energy levels, thermal isolation, and population inversion). For (c), present the separation of variables derivation clearly with proper handling of the radial equation. Conclude with a synthesis noting how these topics span classical electrodynamics, statistical mechanics, and mathematical physics.

  • Part (a): Calculate loss tangent tan δ = σ/(ωε) to classify the medium as good conductor or lossy dielectric, then correctly apply formulas for α, β, η and phase velocity u = ω/β
  • Part (a): Derive H(z,t) using the intrinsic impedance relationship η = E/H with proper vector orientation (aₓ × aᵧ = aᵧ, accounting for the phase of η in complex form)
  • Part (b): Define negative temperature as T < 0 occurring when (∂S/∂U) < 0, occurring in systems with upper energy bound, not 'colder than absolute zero'
  • Part (b): Enumerate restrictions: (i) system must have finite number of energy levels, (ii) thermally isolated (no energy exchange with reservoir), (iii) population inversion required; cite examples like nuclear spin systems or laser media
  • Part (c): Write Laplace's equation in cylindrical coordinates: (1/r)∂/∂r(r∂V/∂r) + (1/r²)∂²V/∂φ² + ∂²V/∂z² = 0
  • Part (c): Apply separation V(r,φ,z) = R(r)Φ(φ)Z(z) to obtain three ODEs: Bessel's equation for R, harmonic equation for Φ, and exponential/trigonometric equation for Z with separation constants
  • Part (c): Identify the physical significance: R(r) involves Bessel functions Jₙ and Yₙ (or modified Bessel Iₙ, Kₙ), Φ(φ) requires single-valuedness giving integer n, Z(z) depends on boundary conditions

Paper II

8 questions · 400 marks
Q1
50M Compulsory solve Quantum mechanics and atomic physics

(a) What is de Broglie concept of matter wave ? Evaluate de Broglie wavelength of Helium that is accelerated through 300 V. (Given mass of proton = Mass of neutron = 1·67×10⁻²⁷ kg) 10 marks (b) An electron in a one-dimensional infinite potential well, defined by V(x) = 0 for -a ≤ x ≤ a and V(x) = ∞ otherwise, goes from n = 4 to n = 2 level and emits photon of frequency 3·43×10¹⁴ Hz. Calculate the width of the well. (Assume Plank's constant h = 6·626×10⁻³⁴ J.S. and mass of electron m = 9·11×10⁻³¹ kg) 10 marks (c) Calculate the magnetic field strength required to observe the NMR spectrum of protons in benzene at 120 MHz. [Given the value of nuclear g-factor gₙ for protons is 5·585] 10 marks (d) Show that the Landé g-factor for pure orbital angular momentum and pure spin angular momentum are 1 and 2 respectively. Further, evaluate the g-factor for the state ³P₁. 10 marks (e) The raising (J₊) and lowering (J₋) operators are defined by J₊ = Jₓ + iJᵧ and J₋ = Jₓ - iJᵧ respectively. Prove the following identities : (i) [Jᵤ, J₊] = ±ℏJ₊ (ii) J₋J₊ = J² - Jᵤ² - ℏJᵤ 10 marks

Answer approach & key points

Solve requires systematic problem-solving across all five sub-parts with equal time allocation (~20% each). Begin with concise conceptual definitions for (a), then proceed to step-by-step calculations for (a)-(c), rigorous derivations for (d)-(e). Structure: direct answers without elaborate introduction, showing all intermediate steps, unit conversions, and final boxed results for each sub-part.

  • (a) State de Broglie hypothesis λ = h/p; derive λ = h/√(2mE) for non-relativistic case; calculate He wavelength using m_He = 4m_p (alpha particle mass) and E = 300 eV, obtaining λ ≈ 8.3×10⁻¹² m
  • (b) Apply infinite square well energy levels E_n = n²π²ℏ²/(8ma²) for well width 2a; use ΔE = E₄ - E₂ = hf to solve for a, obtaining a ≈ 1.5×10⁻⁹ m or width 2a ≈ 3 nm
  • (c) Apply NMR resonance condition hν = gₙμₙB where μₙ = eℏ/(2m_p); solve for B = hν/(gₙμₙ) ≈ 2.82 T
  • (d) Derive g_L = 1 from μ_L = -(e/2m)L and g_S = 2 from μ_S = -(e/m)S; apply Landé formula g_J = 1 + [J(J+1)+S(S+1)-L(L+1)]/[2J(J+1)] for ³P₁ (L=1,S=1,J=1) to get g_J = 3/2
  • (e) Prove [J_z, J_+] = ℏJ_+ and [J_z, J_-] = -ℏJ_- using [J_z, J_x] = iℏJ_y and [J_z, J_y] = -iℏJ_x; prove J_-J_+ = J² - J_z² - ℏJ_z by expanding and using J_x² + J_y² = J² - J_z²
Q2
50M derive Quantum mechanics and atomic structure

(a) Set up the Schrodinger's wave equation for one dimensional potential barrier and obtain the probability of tunneling. 20 marks (b) Show that $E_n = <V>$ in the stationary states of the hydrogen atom. 15 marks (c) (i) Show that for a given principal quantum number $n$, there are $n^2$ possible states of the atom. (ii) An atomic state is denoted by $^4D_{5/2}$. Find the values of $L$, $S$ and $J$. For this state, what should be the minimum number of electrons involved ? Suggest a possible electronic configuration. 7+8=15 marks

Answer approach & key points

Derive the tunneling probability for a 1D potential barrier in part (a) using boundary condition matching; prove the virial theorem relation for hydrogen in (b); enumerate n² degeneracy with proper quantum number counting for (c)(i); and decode the term symbol ^4D_{5/2} to extract L, S, J and suggest a minimal electron configuration for (c)(ii). Allocate approximately 40% time to (a), 30% to (b), and 30% combined to both parts of (c), ensuring each sub-part receives proportional attention to its marks.

  • Part (a): Set up time-independent Schrödinger equation for regions I (x<0), II (0<x<a), and III (x>a) with appropriate wave functions; apply continuity conditions for ψ and dψ/dx at x=0 and x=a; obtain transmission coefficient T = |F/A|² = [1 + (k₁²+k₂²)²sinh²(κa)/(4k₁²k₂²)]⁻¹ ≈ 16E(V₀-E)/V₀² exp(-2κa) for E<V₀
  • Part (b): Apply virial theorem 2⟨T⟩ = ⟨r·∇V⟩ for Coulomb potential V∝1/r; show ⟨T⟩ = -Eₙ/2 and ⟨V⟩ = 2Eₙ; conclude Eₙ = ⟨V⟩/2 + ⟨T⟩ = ⟨V⟩ - ⟨V⟩/2 = ⟨V⟩/2 + ⟨V⟩/2 verification or direct proof using hydrogenic wave functions and expectation value ⟨r⁻¹⟩ = 1/(n²a₀)
  • Part (c)(i): Count states using quantum numbers n, l, m_l: for given n, l ranges 0 to n-1; each l has (2l+1) m_l values; sum Σ(2l+1) from l=0 to n-1 equals n²; alternatively include spin degeneracy factor of 2 to get 2n² for total states
  • Part (c)(ii): Decode term symbol ^4D_{5/2}: 2S+1=4 gives S=3/2; D means L=2; J=5/2; minimum electrons = 3 (for S=3/2 requires at least 3 unpaired electrons); possible configuration: [Ar]3d³4s² (vanadium) or [Ar]3d⁷4s² (cobalt) or 2p²3p¹ excited state
  • Physical significance: Connect tunneling to α-decay (Gamow factor), STM microscopy, and quantum devices; relate hydrogen result to stability of atomic orbits; connect term symbols to atomic spectroscopy and Hund's rules applications
Q3
50M explain Quantum mechanics and atomic physics

(a) What is the spin wave function (for $s=\frac{1}{2}$) if the spin component in the direction of unit vector $\eta$ has a value of $\frac{1}{2}\hbar$ ? 15 marks (b) (i) Why does Stern-Gerlach experiment enjoy so much importance in atomic physics ? (ii) Draw the schematic diagram of this experiment and comment on the shapes of the magnet pole pieces. (iii) Why was the atomic beam of silver used in this experiment ? 20 marks (c) Define Franck-Condon principle. How does it help in explaining the intensity distribution of vibrational-electronic spectra of diatomic molecules. 15 marks

Answer approach & key points

This question demands clear explanation across theoretical derivation, experimental physics, and spectroscopic principles. Allocate approximately 30% time to part (a) for rigorous spinor derivation using rotation matrices, 40% to part (b) covering Stern-Gerlach significance, schematic diagram with shaped pole pieces, and silver atom rationale, and 30% to part (c) for Franck-Condon principle with potential energy curve diagrams. Begin with mathematical formulation, transition to experimental verification, and conclude with spectroscopic application.

  • Part (a): Derivation of spin wave function χ₊(η) = cos(θ/2)χ₊ + e^(iφ)sin(θ/2)χ₋ using direction cosines (θ,φ) of unit vector η, showing eigenvalue equation S·η χ = +(ℏ/2)χ
  • Part (b)(i): Explanation of Stern-Gerlach importance—first direct evidence of space quantization, electron spin discovery, basis for quantum measurement theory and quantum information (qubit realization)
  • Part (b)(ii): Schematic diagram showing oven, collimating slits, inhomogeneous magnetic field with pole pieces shaped as wedge/cylinder or knife-edge to create ∂Bz/∂z ≠ 0, and detection screen
  • Part (b)(iii): Silver atom rationale—single valence electron (5s¹) with J=1/2, zero orbital angular momentum (L=0), no hyperfine splitting complication, high atomic mass minimizing Doppler broadening, thermal vaporization feasibility
  • Part (c): Franck-Condon principle statement (vertical transitions with nuclear positions fixed), explanation using overlap integrals of vibrational wavefunctions |⟨ψv'|ψv''⟩|², intensity distribution in progression and sequences with Condon parabola
Q4
50M calculate Molecular spectroscopy and quantum mechanics

(a) (i) In a diatomic molecule when one constituent atom is replaced by one of its heavier isotopes, what change takes place in the rotational spectrum ? (ii) Calculate the change in rotational constant B when hydrogen is replaced by deuterium in the hydrogen molecule. (iii) Draw the spectra of rigid and non-rigid rotors by using the schematic representation of the rotational energy levels and comment on it. 20 marks (b) (i) Briefly explain the effect of anharmonicity on the vibrational spectra of diatomic molecules. (ii) Calculate the average period of rotation of HCl molecule if it is in the J = 3 state. The internuclear distance and the moment of inertia of HCl are 0·1274 nm and 0·0264×10⁻⁴⁵ kg.m² respectively. 15 marks (c) Obtain the normalized eigenvectors of σₓ and σᵧ matrices. 15 marks

Answer approach & key points

Begin with the directive 'calculate' for the numerical sub-parts (a)(ii), (b)(ii), and (c), while using 'explain', 'draw', and 'obtain' for the descriptive sub-parts. Allocate approximately 40% of time/effort to part (a) given its 20 marks, 30% each to parts (b) and (c). Structure as: brief conceptual introduction → systematic treatment of each sub-part with clear labeling → concluding synthesis on how isotope effects and quantum mechanical treatments reveal molecular structure.

  • For (a)(i): Explain that isotopic substitution increases reduced mass μ, decreases rotational constant B (B ∝ 1/μ), and compresses rotational energy levels leading to closer-spaced spectral lines
  • For (a)(ii): Calculate B_H₂ = ℏ/(4πcI_H₂) and B_D₂ = ℏ/(4πcI_D₂), showing I_D₂ = 2I_H₂ due to doubled reduced mass, hence B_D₂ = B_H₂/2, or explicitly compute numerical values
  • For (a)(iii): Draw energy level diagrams showing equally spaced levels for rigid rotor vs. diverging levels for non-rigid rotor (centrifugal distortion), with corresponding spectral line spacing
  • For (b)(i): Explain anharmonicity introduces cubic term in potential, causes energy level convergence, overtone frequencies as ν₀(1-2x_e), (ν₀-4ν₀x_e), etc., and decreased spacing at higher v
  • For (b)(ii): Calculate rotational period T = 2π/ω = 2πI/√[J(J+1)]ℏ using given I = 0.0264×10⁻⁴⁵ kg.m² and J=3, obtaining T ≈ 1.3×10⁻¹³ s or equivalent
  • For (c): Derive normalized eigenvectors of σₓ = (0 1; 1 0) as (1/√2)(1; ±1) and σᵧ = (0 -i; i 0) as (1/√2)(1; ±i), showing explicit normalization and orthogonality
Q5
50M Compulsory explain Nuclear physics, superconductors, semiconductor devices, digital electronics

(a) If the nuclear force is charge independent and a neutron and proton form a bound state then why is there no bound state for two neutrons ? What information does this provide on the nucleon-nucleon force ? (10 marks) (b) Explain why each of the following particles cannot exist according to the quark model. (i) A Baryon of spin 1 and (ii) An anti-Baryon of electric charge +2 (10 marks) (c) Explain why Type-II superconductor is better than Type-I superconductor in the application of superconductor magnets. (10 marks) (d) Why is the Field Effect Transistor (FET) called Unipolar Transistor ? Discuss how it is superior than Bipolar Junction Transistor. (10 marks) (e) Why NAND and NOR gates are called universal gates ? Give the logic diagram, Boolean equation and the truth table of a X-OR gate. (10 marks)

Answer approach & key points

The directive 'explain' demands clear causal reasoning and mechanistic understanding across all sub-parts. Allocate approximately 20% time each to (a), (b), (c), (d), and (e) as all carry equal marks. Structure with brief introductions for each sub-part, followed by systematic causal explanations, and conclude with synthesizing remarks on nuclear forces, quark confinement, and device applications. For (b)(i)-(ii), treat both as mandatory; for (e), ensure all three components (NAND/NOR universality, XOR diagram, Boolean equation, truth table) are addressed.

  • (a) Explains why dineutron is unbound despite charge-independent nuclear force: Pauli exclusion principle forbids identical fermions in same state, so nn system must be in spin-triplet (antisymmetric space) with reduced overlap vs deuteron's spin-singlet; cites tensor force and spin-dependence of nuclear force
  • (b)(i) Demonstrates baryon spin-1 impossibility: three quarks (spin-1/2 each) can only combine to total spin 1/2 or 3/2 via angular momentum coupling, never spin-1; shows explicit quark spin wavefunction construction
  • (b)(ii) Proves anti-baryon charge +2 impossibility: anti-baryon has three antiquarks, each with charge +1/3 or +2/3, giving maximum possible charge +2 only if all three are anti-up (+2/3 each), but this violates color singlet requirement (antisymmetric color × antisymmetric flavor × symmetric spin)
  • (c) Contrasts Type-I (complete Meissner effect, H < Hc) vs Type-II (vortex state, Hc1 < H < Hc2): explains flux penetration via Abrikosov vortices, higher critical fields enabling superconducting magnets; mentions Indian contributions (K. S. Novoselov's graphene work context, or indigenous superconductor research at BARC/IITs)
  • (d) Defines FET as unipolar (single carrier type: electrons in n-channel or holes in p-channel) vs BJT (bipolar: both carriers); lists superiority: high input impedance, voltage-controlled, negligible gate current, thermal stability, smaller size, faster switching; mentions Indian semiconductor initiatives (ISRO's indigenous fabrication)
  • (e) Proves NAND/NOR universality by constructing NOT, AND, OR from each; provides complete XOR: logic diagram with NAND gates, Boolean expression Y = A⊕B = A'B + AB' = (A+B)(A'+B'), truth table with all four input combinations
Q6
50M derive Nuclear shell model, crystal structures, semi-empirical mass formula

(a) Show that for a specific value (n, l), there exists a large degeneracy relative to the energy characterized by the quantum number (N). Find the shell closures and the magic numbers predicted by harmonic oscillator potential. (15 marks) (b) Considering atoms hard, uniform spheres, find the number of atoms per unit cell and packing fraction for simple cubic, bcc and fcc structures. (15 marks) (c) Write down the Weizsäcker semi-empirical mass formula and explain each term. Explain why ₉₂²³⁸U nuclide is an α-emitter and not a β⁻-emitter ? (10+10 marks)

Answer approach & key points

Begin with a concise introduction linking nuclear structure, crystallography and nuclear stability. For part (a), derive the degeneracy formula g_N = (N+1)(N+2)/2 and identify magic numbers 2, 8, 20, 28, 50, 82, 126 using N = 2(n-1)+l. For part (b), calculate packing fractions π/6, π√3/8 and π√2/6 with clear unit cell diagrams. For part (c), state the full Weizsäcker formula with all seven terms, then apply Q-value calculations to show ²³⁸U prefers α-decay over β⁻ due to higher binding energy per nucleon and Coulomb barrier considerations. Allocate ~35% effort to (a), ~30% to (b), and ~35% to (c) including the comparative analysis.

  • Part (a): Derivation of total quantum number N = 2(n-1) + l and proof that degeneracy g_N = (N+1)(N+2)/2 for 3D isotropic harmonic oscillator
  • Part (a): Enumeration of shell closures at N = 0,1,2,3,4,5,6 leading to magic numbers 2, 8, 20, 40, 70, 112, 168; correction to observed magic numbers 2, 8, 20, 28, 50, 82, 126 with spin-orbit coupling mention
  • Part (b): Calculation of atoms per unit cell (1, 2, 4) and packing fractions (π/6 ≈ 0.52, π√3/8 ≈ 0.68, π√2/6 ≈ 0.74) for SC, BCC, FCC with proper geometric derivation involving atomic radius and lattice parameter relations
  • Part (c): Complete Weizsäcker formula with volume, surface, Coulomb, asymmetry, pairing, shell correction and pairing terms with correct coefficients; physical explanation of each term
  • Part (c): Q-value calculation for α-decay (Q_α ≈ 4.27 MeV, spontaneous) versus β⁻-decay energetics; explanation using N/Z ratio, Coulomb repulsion dominance, and liquid drop model predictions for heavy nuclei (A>210)
Q7
50M explain Solid state physics and nuclear physics

(a) Explain the drawbacks of Einstein's theory of specific heat and how it was overcome by Debye. 20 marks (b) A neutron and a proton can undergo radiative capture at rest: n + p → d + γ Find the energy of the photon emitted in this capture. Is the recoil of the deuteron important? 15 marks (c) Compare the dependence of resistance on temperature of a superconductor with that of a normal conductor. Describe briefly the formation of Cooper pairs. 15 marks

Answer approach & key points

Begin with a brief introduction acknowledging the historical development of quantum theories of specific heat. For part (a), spend approximately 40% of effort explaining Einstein's assumption of independent oscillators and Debye's improvement using a continuous spectrum of phonon modes with the Debye cutoff. For part (b), allocate 30% to derive the photon energy using mass-energy equivalence and binding energy of deuteron (~2.224 MeV), then assess recoil energy significance. For part (c), use remaining 30% to contrast resistance-temperature curves and explain Cooper pair formation via electron-phonon interaction. Conclude by noting the unifying theme of quantum effects in condensed matter.

  • Part (a): Einstein's theory assumes all atoms vibrate with same frequency ν_E, leading to C_V → 0 exponentially at low T instead of T³ law; Debye treats solid as continuous elastic medium with cutoff frequency ν_D, introducing Debye temperature Θ_D and density of states g(ν) ∝ ν²
  • Part (a): Debye's integral expression for specific heat and its correct prediction of C_V ∝ T³ at T << Θ_D and Dulong-Petit law at T >> Θ_D; mention limitations at intermediate T
  • Part (b): Application of mass-energy conservation: E_γ = [m_n + m_p - m_d]c² = B_d (binding energy of deuteron) ≈ 2.224 MeV; recoil energy E_recoil = E_γ²/(2m_dc²) ≈ 1.3 keV is negligible (~0.06%)
  • Part (c): Normal conductor: resistance increases with T due to enhanced phonon scattering (ρ ∝ T for T > Θ_D, ρ ∝ T⁵ at low T); superconductor: zero resistance below T_c with sharp transition
  • Part (c): Cooper pair formation via attractive interaction mediated by phonon exchange; electrons with opposite k and spin form bound state with energy gap; coherence length and BCS theory essence
Q8
50M derive Semiconductors, X-ray diffraction and particle physics

(a) Show that for an n-type semiconductor, the Fermi level lies midway between the donor states and the conduction band edge at low temperature (assuming Eᵥ = 0). 20 marks (b) The wavelength of a prominent X-ray line from a copper target is 0·1512 m. The radiation, when diffracted with (111) plane of a crystal with fcc structure, corresponded to a Bragg angle of 20·2°. If the density of the crystal is 2698 kg/m³ and atomic weight is 26·98 kg/k mol, calculate the Avogadro number. 15 marks (c) Which of the following decays are allowed and which are forbidden? If the decay is allowed, state which interaction is responsible. If it is forbidden, state which conservation law its occurrence would violate. (a) n → p + e⁻ + ν̄ₑ (b) Λ° → π⁺ + π⁻ (c) π⁻ → e⁻ + γ (d) π° → e⁻ + e⁺ + νₑ + ν̄ₑ (e) π⁺ → e⁻ + e⁺ + μ⁺ + νᵤ 15 marks

Answer approach & key points

Derive the Fermi level position for n-type semiconductor in part (a) using charge neutrality and appropriate approximations at low temperature. For part (b), apply Bragg's law to find interplanar spacing, then use fcc geometry and density formula to calculate Avogadro number. For part (c), analyze each decay using conservation laws (charge, baryon number, lepton number, strangeness, energy-momentum) to determine allowed/forbidden status and identify the responsible interaction. Allocate approximately 40% time to (a), 30% to (b), and 30% to (c) based on mark distribution.

  • Part (a): Derivation showing E_F = (E_C + E_D)/2 using charge neutrality condition n_0 = n_D+ at low T, with proper assumptions about donor ionization and negligible intrinsic carriers
  • Part (b): Application of Bragg's law (2d sin θ = nλ), calculation of d_111 for fcc, relation between lattice parameter and atomic density, and final calculation of N_A ≈ 6.02 × 10^23 mol^-1
  • Part (c)(i): n → p + e⁻ + ν̄ₑ is allowed weak decay (β-decay) conserving all quantum numbers
  • Part (c)(ii): Λ° → π⁺ + π⁻ is forbidden as it violates baryon number conservation (B=1 → B=0)
  • Part (c)(iii): π⁻ → e⁻ + γ is forbidden as it violates lepton number conservation (L=0 → L=1) and angular momentum
  • Part (c)(iv): π° → e⁻ + e⁺ + νₑ + ν̄ₑ is forbidden as it violates energy conservation (m_π° < 2m_e + E_ν)
  • Part (c)(v): π⁺ → e⁻ + e⁺ + μ⁺ + νᵤ is forbidden as it violates charge conservation (+1 → +1-1+1+0 = +1 actually check: +1 → -1+1+1+0 = +1, but violates lepton family number and energy)

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